The Vampire Diaries characters Damon (Ian Somerhalder) and Elena (Nina Dobrev) have been voted the best TV couple of all time. E! News started its contest with 64 iconic TV couples, including Ross and Rachel from Friends, Buffy and Angel from Buffy, the Vampire Slayer and Carrie and Big from Sex and the City. Damon and Elena won by just three percent -- Rachel and Finn from Glee came in a super close second. In response to her character's win, Dobrev said "We're incredibly flattered and excited about it. It is really awesome!" However, the I Love Lucy fan admitted that she felt like Ricky and Lucy were more deserving.